Since not a lot of peoples post I guess I will propose a few others if you need em. I'm unsure about proposing military jobs. I guess those would probably already be filled so I will stick to civilians.
scientists and biologists of multiple specialised area (marine life, wildlife, geology, etc.)
Popular entertainers like a popular band or a single celebrity (I dont think a huge percentage of the VIP are going to be entertainers to be honest considerin the many ways someone can become a millionaire. I dont know what you planned tho)
Powerfull criminals who paid under the table for a seat?
Prominent political figure of a party of your choosing maybe? Maybe even their whole cabinet. I want to give environmentalists a new chance at politic. They deserve it XD (This lead me to a question actualy. How will politic be handled post landing?)
Specialised engineers maybe? Could maybe lead to specialising in a certain kind of energy for the colony to use between stuff like nuclear or renewable. o
Or for special infrastructure projects maybe? (massive dam, offshore wind farm, big subway system for safer transport on the planet maybe? Idk. Dont want to propose stuff too big either.)
I know there's a lot of "specialised" but splitting a job in categories really give more and considering you need 100 you need all you can get.